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Fuel for Thought
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Fuel for Thought

Deep diving energy-dense nuclear fuel

Welcome back to Decouple, the best source for cutting-edge analysis on nuclear energy, with weekly interviews by Chris Keefer. Watch on YouTube, Spotify, or Apple.

Cover photo: uranium fuel pellet. Photo by NRC.

Today, we talk uranium nuclear fuel.

I spoke with MIT's Professor Koroush Shirvan, who rejoins me after our first interview on Small Modular Reactors. Now, we dive into the hidden complexities of nuclear fuels. From early fuel experiments that saw uranium rods turn into spaghetti-like structures under neutron bombardment to the intricate economics shaping the future of fuels like TRISO, Shirvan offers clear insights into the realities behind nuclear power’s remarkable yet challenging fuel technologies.

Read on and listen to discover how history shaped today's dominant fuel choices, why accident-tolerant innovations are critical, and about the economic realities that could either launch or limit the nuclear renaissance.

Watch now on YouTube.

We talk about

  • Extraordinary energy density of nuclear fuels compared to fossil fuels

  • Evolution from unstable uranium metal fuels to stable ceramics like uranium oxide

  • Complex transmutation occurring within nuclear fuel rods

  • Dominance of uranium oxide fuel in global reactors

  • Importance and challenges of zirconium-based cladding

  • Extensive time required for developing and qualifying new nuclear fuels

  • Economics and rising costs of fuel enrichment, especially for High-Assay Low-Enriched Uranium (HALEU)

  • Detailed exploration of TRISO fuel, its benefits, and high manufacturing costs

  • Comparative fuel cost analysis: CANDU, LWR, TRISO, and natural gas

  • Impact of enrichment and fabrication capabilities on nuclear fuel economics

Deeper Dive

Nuclear fuels have always benefitted from staggering energy density. The original promise of uranium—70,000 times more energy per kilogram compared to natural gas—is compelling. Yet, Professor Shirvan reminds us that practical limitations significantly erode this advantage. Uranium's complexity, from mining through enrichment and encapsulation, strips away much of this initial promise. Even so, the sheer energy density remains unmatched.

Log Scale
“Log Scale” by the ever-brilliant Randall Munroe of XKCD

Historically, nuclear fuels evolved from metallic uranium to ceramic forms because metals simply couldn’t withstand the intense neutron bombardment. Early experiments produced disturbing results—uranium rods swelling into "spaghetti-like" shapes after mere days. Hence, ceramics like uranium oxide emerged, stable enough to handle harsh reactor conditions and chemically inert in air or water exposure.

"Historically, uranium oxide fuel emerged because metallic uranium turned into spaghetti under neutron bombardment." – Koroush Shirvan

The famous “yellowcake,” a mixture of compounds including uranium oxides like triuranium octoxide (U3O8), uranium dioxide (UO2), and uranium trioxide (UO3). Photo from IAEA.
Uranium dioxide (left) and sintered uranium dioxide pellets (right). Photos by Chemolunatic, CC BY-SA 4.0

Zirconium alloys became the standard for cladding due to their neutron transparency. Yet, these materials are not without issues, particularly in accident scenarios where they can rapidly oxidize and fail. Shirvan stresses the ongoing importance of developing accident-tolerant fuels (ATFs). These ATFs could dramatically reduce risks by maintaining structural integrity longer under extreme conditions, buying crucial response time in emergencies.

Historical photo of reactor fuel assembly production, circa 1971. Zircaloy tubes that hold uranium oxide fuel pellets are moved through a series of "baths" and cleaning processes in a preliminary fuel production step. Photo by US Department of Energy.

TRISO fuel, which encapsulates uranium particles in ceramic layers, promises enhanced safety and higher operating temperatures. Shirvan outlines its early adoption in high-temperature gas reactors, its decline due to regulatory and economic barriers, and its current renaissance. Yet, TRISO's complexity—and resulting higher enrichment—drives costs up significantly. Without scale, it remains economically daunting.

Cross section view of the inside of a TRISO nuclear fuel sphere, showing coated uranium oxide particles dispersed within a graphite bulk. Photo from US Department of Energy.

Shirvan clarifies how enrichment levels exponentially impact fuel costs. High-Assay Low-Enriched Uranium (HALEU) required by advanced reactors costs magnitudes more, largely because of strict regulatory safeguards and limited production facilities. This financial barrier starkly contrasts with natural gas, despite uranium’s theoretical energy density advantage.

"When you go above 10% enrichment, you're looking at a different category of operation classification. And so what that means is that you have to have different form of quality assurance related to safeguards of this material." - Koroush Shirvan

Facing Urgency, DOE Moves to Demonstrate HALEU Fuel Production Capability  for Advanced Nuclear Reactors
Comparison of uranium-235 content of different classifications of uranium fuel. Image from Centrus Energy.

Looking ahead, Shirvan sees potential yet realism. Optimistically, with substantial investment, TRISO costs could be reduced, becoming competitive at scale. Realistically, however, he acknowledges considerable uncertainty—investment risks, prolonged regulatory timelines, and market inertia might stymie rapid progress. Nuclear's economic future thus hinges precariously on decisions made today about fuels, infrastructure, and innovation.

"Economics will ultimately determine nuclear’s future—innovation must drive down costs or it won’t survive." – Koroush Shirvan

Watch Koroush Shirvan’s previous interview on Decouple.

Timestamps

  • 00:00 Introduction

  • 03:05 Historical Evolution and Energy Density

  • 09:44 Chemistry and Complexity of Nuclear Fuel

  • 14:15 Why Uranium Oxide Dominates

  • 21:09 Fuel Cladding Explained

  • 29:23 Accidents and Fuel Failures

  • 35:24 Challenges in Fuel Development

  • 40:41 TRISO Fuel: Past, Present, and Potential

  • 50:30 Economics of HALEU

  • 01:05:37 Comparative Costs and Future Realities

Keywords

Nuclear fuels, Uranium oxide, Zirconium cladding, Accident-tolerant fuels (ATF), TRISO particles, High-Assay Low-Enriched Uranium (HALEU), Nuclear economics, Fuel enrichment, Advanced reactors, Nuclear renaissance

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